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Université de Fribourg

Electron collisions with CO: Elastic and vibrational excitation cross sections

Allan, Michael

In: Physical Review A, 2010, vol. 81, no. 04, p. 042706

Absolute differential elastic and vibrational excitation cross sections up to v=11 were measured for CO in scattering angle ranges extending to 180° at energies between 0.2 and 5 eV (and an elastic measurement at 10 eV). The lowest angles were 0° for inelastic scattering and between 5° and 20° for elastic scattering, depending on energy. Integral cross sections were derived by integrating...

Université de Fribourg

Absolute angle-differential elastic and vibrational excitation cross sections for electron collisions with tetrahydrofuran

Allan, Michael

In: Journal of Physics B: Atomic, Molecular and Optical Physics, 2007, vol. 40, no. 17, p. 3531

Absolute angle-differential elastic and vibrational excitation cross sections for electron collisions with tetrahydrofuran were measured in the energy range 0.1–20 eV, extending existing measurements to lower energies. The elastic cross sections were measured as a function of scattering angle from 10° to 180° at energies of 2 eV, 6 eV, 10 eV and 20 eV, and as a function of electron energy at...

Université de Fribourg

Improved techniques of measuring accurate electron - molecule cross sections near threshold and over a large angular range

Allan, Michael

In: AIP Conference Proceedings, 2007, vol. 901, p. 107-116

Methods to measure absolute differential elastic and vibrational excitation cross sections using an electron spectrometer with a magnetic angle changer are discussed. Emphasized are the need to by-pass drifts and to properly correct for the instrumental response function when angle of detection or electron energy are varied. The results are illustrated with cross sections in nitrogen, methane and...

Université de Fribourg

Threshold phenomena in electron-molecule scattering

Allan, Michael

In: Physica Scripta, 2004, vol. T110, p. 161-165

Absolute differential cross sections were measured at 135° for the elastic and the vibrationally inelastic electron scattering from threshold to 12 eV, with emphasis on the threshold region. In addition, relative dissociative electron attachment spectra were measured from 0.1 to 3.5 eV. Structures of vibrational origin were observed at energies below 1 eV, well below the ²Π shape resonance, in...

Université de Fribourg

Structures in elastic, vibrational, and dissociative electron attachment cross sections in N₂O near threshold

Allan, Michael ; Skalický, Tomás

In: Journal of Physics B: Atomic, Molecular and Optical Physics, 2003, vol. 36, no. 16, p. 3397-3409

Absolute differential cross sections were measured at 135° for the elastic and the vibrationally inelastic electron scattering from threshold to 12 eV, with emphasis on the threshold region. In addition, relative dissociative electron attachment spectra were measured from 0.1 to 3.5 eV. Structures of vibrational origin were observed at energies below 1 eV, well below the ²Π shape resonance, in...

Université de Fribourg

Selectivity in the excitation of Fermi-coupled vibrations in CO₂ by impact of slow electrons

Allan, Michael

In: Physical Review Letters, 2001, vol. 87, no. 3, p. 033201

Improvement of resolution of a gas phase hemispherical electron spectrometer (to 7 meV FWHM) permitted separate measurements of the excitation of each member of the well known Fermi dyad in CO₂ by impact of slow electrons. Absolute differential cross sections at a scattering angle of 135° were measured as a function of electron energy. The excitation was found to be highly selective both via...

Université de Fribourg

Electron collisions with formic acid monomer and dimer

Allan, Michael

In: Physical Review Letters, 2007, vol. 98, no. 12, p. 123201

Processes induced by the attachment of slow electrons to formic acid and its hydrogen-bonded dimer were studied. The elastic cross section and the cross section for the excitation of low quanta of discrete vibrations were found to be of a similar magnitude for both targets. A dramatic difference was found in the excitation of a vibrational quasicontinuum in the 1–2 eV range with the ejection of...

Université de Fribourg

Study of resonances in formic acid by means of vibrational excitation by slow electrons

Allan, Michael

In: Journal of Phyics B: Atomic, Molecular and Optical Physics, 2006, vol. 39, no. 14, p. 2939-2947

Absolute differential elastic and vibrational excitation cross sections have been measured for formic acid at 135° from threshold to 5 eV. Most vibrationally inelastic cross sections have a narrow peak at threshold, followed by a broadband with a boomerang structure due to the known π* shape resonance. The cross section for the excitation of the O–H stretch vibration behaves differently, it...

Université de Fribourg

Absolute angle-differential cross sections for electron-impact excitation of neon atoms from threshold to 19.5 eV

Allan, Michael ; Franz, K. ; Hotop, Hartmut ; Zatsarinny, O. ; Bartschat, K.

In: Journal of Physics B: Atomic, Molecular and Optical Physics, 2006, vol. 39, p. L139-L144

Absolute angle-differential cross sections for electron-impact excitation of neon atoms to the four levels with the (2p⁵3s) configuration have been determined both experimentally and theoretically for incident energies from threshold up to 19.5 eV at scattering angles of 135° and 180°. Excellent agreement between the experimental data and theoretical predictions, obtained by a Breit–Pauli...

Université de Fribourg

Decay channels in the dissociative electron attachment to NO

Allan, Michael

In: Journal of Physics B: Atomic, Molecular and Optical Physics, 2004, vol. 37, p. L359-L363

Kinetic energy spectra of O⁻ from dissociative electron attachment (DEA) to NO were measured at 7.6, 8.0, 9.0 and 10.0 eV electron energy using a spectrometer with hemispherical energy selectors for both the incident electrons and the resulting ions. The measurements were performed at 10°, 30°, 90° and 135°. The capacity of the spectrometer to detect both slow and fast ions was verified and...