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    Université de Fribourg

    Complexation behaviour of chiral tetradentate polypyridines derived from α-pinene

    Düggeli, Mathias ; Bonte, Christophe ; Zelewsky, Alexander von

    In: Inorganica Chimica Acta, 2005, vol. 358(1), p. 41-49

    A series of ligands, where two pinene-bipyridine moieties are either connected directly, or through a p-xylene bridge are investigated with respect to their complexation behaviour in solution. The bridged [5,6]-CHIRAGEN[p-xyl] ligands, which are substituted in 5' or 6' positions show self-assembly reactions, which lead to similar supramolecular species as the unsubstituted bis-pinene-bipyridines...