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Photoremovable protecting groups in chemistry and biology: reaction mechanisms and efficacy

Klán, Petr ; Šolomek, Tomáš ; Bochet, Christian G. ; Blanc, Aurélien ; Givens, Richard ; Rubina, Marina ; Popik, Vladimir ; Kostikov, Alexey ; Wirz, Jakob

In: Chemical Reviews, 2013, vol. 113, no. 1, p. 119–191

Isotope effects in photochemistry: application to chromatic orthogonality

Blanc, Aurélien ; Bochet, Christian G.

In: Organic Letters, 2007, vol. 9, no. 14, p. 2649-2651

The main challenge in developing new wavelength-specific photolabile protecting groups is the rigorous control of the photolysis rate. This rate is controlled by two factors: the chromophore absorbance and the reaction quantum yield. Fine-tuning the properties by changing substituents or structural features is difficult, because both factors are independently affected. By the use of the kinetic...