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Université de Neuchâtel

1,1′-Ferrocene dicarboxylic acid pyridin-4-yl ester: A new bidentate ligand in arene ruthenium chemistry

Auzias, Mathieu ; Therrien, Bruno ; Süss-Fink, Georg

In: Inorganic Chemistry Communications, 2007, vol. 10, no. 11, p. 1239-1243

1,1′-Ferrocene dicarboxylic acid pyridin-4-yl ester (1) is prepared from 1,1′-ferrocene dicarbonyl chloride and 4-hydroxypyridine. This new bidentate ferrocenoyl ligand reacts with the monocationic complex [(η6-p-cymene)2Ru2 (μ-OH)3]+ to give the dicationic complex...

Université de Fribourg

1,2,3-triazolylidenes as versatile abnormal carbene ligands for late transition metals

Mathew, Paulson ; Neels, Antonia ; Albrecht, Martin

In: Journal of the American Chemical Society, 2008, vol. 130, no. 41, p. 13534–13535

The [3 + 2] cycloaddition of azides and acetylenes followed by nitrogen quaternization was applied for the generation of novel and highly modular triazolium salts. The selective substitution of the 1,3,4-substitution pattern presets such salts as precursors for a new class of abnormal carbene ligands, thus expanding the family of these high-impact ligands. Metalation of the triazolium salts is...

Université de Neuchâtel

1,2-Bis-N-[2’-(diphenylphosphanyl)benzoyl]diaminobenzene, a New Chelating Ligand with Versatile Coordination Properties

Burger, Sylvain ; Therrien, Bruno ; Süss-Fink, Georg

In: European Journal of Inorganic Chemistry, 2003, vol. 17, p. 3099 - 3103

1,2-Bis-N-[2’-(diphenylphosphanyl)benzoyl]diaminobenzene (dppbH; 1) was prepared by peptidic coupling and shown to exist, in the solid state, in the form of hydrogen-bonded dimers by single-crystal X-ray structure analysis. As expected, 1 reacts with [MCl2 (cod)] (M = Pd, Pt; cod = cyclooctadiene) to form square-planar complexes. However, in the case of palladium...

Université de Neuchâtel

1,3-Dipolar cycloadditions : click chemistry for a new synthesis of 5-substituted tetrazoles and applications in organocatalysis

Aureggi, Valentina ; Neier, Reinhard (Dir.) ; Sedelmeier, Gottfried (Codir.)

Thèse de doctorat : Université de Neuchâtel, 2007 ; Th.1959.

Tetrazoles are a class of heterocycles with a wide range of applications in medicinal chemistry and in material sciences 1. However a versatile method to synthesize tetrazoles through safe protocols is still highly desirable. Indeed each of the general known procedures uses either toxic metals, expensive reagents, harsh reaction conditions and may lead to the formation of dangerous hydrazoic acid...

Université de Fribourg

1,4-Dimethylenespiropentane: a unique model system for studying fermi resonance in raman optical activity

Hug, Werner ; Haesler, Jacques ; Kozhushkov, Sergei I. ; Meijere, Armin de

In: ChemPhysChem, 2007, vol. 8, no. 8, p. 1161 - 1169

The C₂-symmetric title compound, a small, rigid hydrocarbon molecule with two distinct, strongly interacting vibrational chromophores, represents a unique model system for testing computational approaches to Raman optical activity (ROA) beyond the isolated molecule and the harmonic approximation. We show that the experimental Raman and ROA spectra are marked by the presence of strong Fermi...

Université de Fribourg

¹⁸²Tungsten Mössbauer spectroscopy of heteropolytungstates

Bochet, Christian G. ; Draper, Thérèse ; Bocquet, Bernard ; Pope, Michael T. ; Williams, Alan F.

In: Dalton Transaction, 2009, vol. 26, p. 5127-5131

The tungsten-182 Mössbauer spectra of a series of Keggin structure heteropolytungstates, [EW₁₂O₄₀]ⁿ⁻ are reported. There is a very considerable variation in quadrupole coupling at the tungsten nucleus indicating considerable asymmetry in the electron distribution for the more electronegative elements E. The quadrupole coupling correlates well with the structural data, in particular...

Université de Neuchâtel

(1S,3S,7R)-3-methyl-α-himachalene from the male sandfly Lutzomyia longipalpis (Diptera: Psychodidae) induces neurophysiological responses and attracts both males and females

Spiegel, C.N. ; Jeanbourquin, P. ; Guerin, Patrick M. ; Hooper, A.M. ; Claude, S. ; Tabacchi, R. ; Sano, S. ; Mori, K.

In: Journal of Insect Physiology, 2005, vol. 51, no. 12, p. 1366-1375

Lutzomyia longipalpis adult males form leks on or near hosts and release (1S,3S,7R)-3-methyl-α-himachalene from their tergal glands to lure females to the same site for mating and feeding. Here we have examined whether the male-produced attractant could also serve as a male aggregation stimulus. High resolution chiral capillary gas chromatography analysis of male...

Université de Neuchâtel

2-(2-Naphthyl)-1,3-dioxane

Thevenet, Damien ; Neier, Reinhard ; Stoeckli-Evans, Helen

In: Acta Crystallographica Section E : Structure Reports Online, 2010, vol. E66, no. 2, p. o473-o474, sup1-8

The title compound, C14H14O2, crystallizes in the chiral monoclinic space group P21. This acetal is composed of a planar naphthalene ring with a 1,3-dioxane ring substituent, which has a chair conformation. In the crystal structure, symmetry-related molecules are connected via a weak C-H ··· O interaction to form a helical chain propagating in [010]. While there are...