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Bimetallic ruthenium–tin chemistry: Synthesis and molecular structure of arene ruthenium complexes containing trichlorostannyl ligands

Therrien, Bruno ; Thai, Trieu-Tien ; Freudenreich, Julien ; Süss-Fink, Georg ; Shapovalov, Sergey S. ; Pasynskii, Alexandr A. ; Plasseraud, Laurent

In: Journal of Organometallic Chemistry, 2010, vol. 695, no. 3, p. 409-414

A series of neutral, anionic and cationic arene ruthenium complexes containing the trichlorostannyl ligand have been synthesised from SnCl2 and the corresponding arene ruthenium dichloride dimers [(η6-arene)Ru(μ2-Cl)Cl]2 (arene = C6H6, PriC6H4Me). While the reaction with triphenylphosphine...