Université de Neuchâtel

Sawhorse-type diruthenium tetracarbonyl complexes containing porphyrin-derived ligands as highly selective photosensitizers for female reproductive cancer cells

Schmitt, Frédéric ; Auzias, Mathieu ; Štěpnička, Petr ; Sei, Yoshihisa ; Yamaguchi, Kentaro ; Süss-Fink, Georg ; Therrien, Bruno ; Juillerat-Jeanneret, Lucienne

In: Journal of Biological Inorganic Chemistry, 2009, vol. 14, no. 5, p. 693-701

Diruthenium tetracarbonyl complexes of the type [Ru2 (CO)4(μ2-η2-O2CR)2L2] containing a Ru–Ru backbone with four equatorial carbonyl ligands, two carboxylato bridges, and two axial two-electron ligands in a sawhorse-like geometry have been synthesized with porphyrin-derived substituents in the axial ligands...

Université de Neuchâtel

Hydrogen-bonded systems between monocarboxylic acids and the trinuclear cluster cation [H3Ru3(C6H6)(C6Me6)2(O)]+ : cold-spray ionisation mass spectroscopic and X-ray crystallographic studies

Therrien, Bruno ; Vieille-Petit, Ludovic ; Süss-Fink, Georg ; Sei, Yoshihisa ; Yamaguchi, Kentaro

In: Journal of Organometallic Chemistry, 2004, vol. 689, p. 2820-2826

The hydrogen-bonded systems formed between monocarboxylic acid derivatives and the trinuclear arene-ruthenium cluster cation [H3Ru3(C6H6)(C6Me6)2(O)]+ (1) have been studied in solution by cold-spray ionisation mass spectroscopy (CSI-MS) and in the solid state by single-crystal X-ray structure analysis...