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Development of iron catalysts for hydrogenation and polymerization

Raemy, Manuel ; Jenny, Titus (Dir.) ; Bochet, Christian (Codir.)

Thèse de doctorat : Université de Fribourg, 2003 ; no 1413.

In the scope of this work, a series of new, easy to prepare iron hydrogenation catalysts have been introduced. Different aspects of this new hydrogenation catalysts such as iron source, activation reagent, substrates and efficiency were investigated. A ligand-free catalyst, prepared from an iron(II) chloride suspension activated with diisobutylaluminiumhydride (DIBAH), showed the highest...