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    Université de Fribourg

    Low-energy electron attachment to SF₆ molecules: Vibrational structure in the cross-section for SF₆⁻ formation up to 1 eV

    Braun, M. ; Ruf, M.-W. ; Hotop, Hartmut ; Allan, Michael

    In: Chemical Physics Letters, 2006, vol. 419, p. 517–522

    In high resolution electron attachment to SF₆, cusp structure due to interchannel coupling has been observed in the cross-section for SF₅⁻ formation at the thresholds for vibrational excitation of the SF₆(v₁) mode up to v₁ = 10. It is superimposed on the broad band peaking around 0.55 eV which has been previously attributed to attachment into a repulsive potential...

    Université de Fribourg

    Low-energy electron attachment to the dichlorodifluoromethane (CCl₂F₂) molecule

    Graupner, K. ; Haughey, S. A. ; Field, T. A. ; Mayhew, C. A. ; Hoffmann, T. H. ; May, Olivier ; Fedor, Juraj ; Allan, Michael ; Fabrikant, Ilya I. ; Illenberger, E. ; Braun, M. ; Ruf, M.-W. ; Hotop, Hartmut

    In: The Journal of Physical Chemistry A, 2010, vol. 114, no. 3, p. 1474–1484

    Results from a joint experimental study of electron attachment to dichlorodifluoromethane (CCl₂F₂) molecules in the gas phase are reported. In a high resolution electron beam experiment involving two versions of the laser photoelectron attachment method, the relative cross section for formation of the dominant anion Cl⁻ was measured over the energy range 0.001−1.8 eV at the gas...