Université de Fribourg

Evanescent-wave dynamic light scattering at an oil-water interface: Diffusion of interface-adsorbed colloids

Stocco, Antonio ; Mokhtari, Tahereh ; Haseloff, Günter ; Erbe, Andreas ; Sigel, Reinhard

In: Physical Review E, 2011, vol. 83, no. 1, p. 011601

A light-scattering goniometer for evanescent-wave dynamic light scattering (EWDLS) measurements at a liquid-fluid interface is introduced, and used for measurements on two charge-stabilized polystyrene colloid systems adsorbed to alkane-water interfaces. The goniometer allows an independent variation of the penetration depth and the scattering vector components parallel and perpendicular to a...

Université de Fribourg

Light scattering near and from interfaces using evanescent wave and ellipsometric light scattering

Sigel, Reinhard

In: Current Opinion in Colloid & Interface Science, 2009, vol. 14, no. 6, p. 426-437

The broad range of interface light scattering investigations in recent years shows the power and the versatility of these techniques to address new and open questions in colloid and interface science and the soft condensed matter field. Structural information for polymers, liquid crystals, or colloids close to planar or spherical colloidal interfaces are either captured with long range light...

Université de Fribourg

Separation of coherent and incoherent scattering contributions in ellipsometric light scattering experiments on latex mixtures

Erbe, Andreas ; Tauer, Klaus ; Sigel, Reinhard

In: Langmuir, 2009, vol. 25, no. 5, p. 2703–2710

Mixtures of poly(styrene) latices were used to vary the sample polydispersity for an investigation of polydispersity effects on ellipsometric light scattering (ELS) data. A procedure for high-accuracy ELS measurements is presented and the experimental distinction of coherent and incoherent scattering contributions is demonstrated. The ellipsometric parameters tan(ΨQ) and Δ are solely...

Université de Fribourg

Dynamics at the air-water interface revealed by evanescent wave light scattering

Stocco, A. ; Tauer, K. ; Pispas, S. ; Sigel, Reinhard

In: The European Physical Journal E, 2009, vol. 29, no. 1, p. 95-105

A new tool to study surface phenomena by evanescent wave light scattering is employed for an investigation of an aqueous surface through the water phase. When the angle of incidence passes the critical angle of total internal reflection, a high and narrow scattering peak is observed. It is discussed as an enhancement of scattering at critical angle illumination. Peak width and height are affected...

Université de Fribourg

Glycopolymer vesicles with an asymmetric membrane

Schlaad, Helmut ; You, Liangchen ; Sigel, Reinhard ; Smarsly, Bernd ; Heydenreich, Matthias ; Mantion, Alexandre ; Mašić, Admir

In: Chemical Communications, 2009, p. 1478 - 1480

Direct dissolution of glycosylated polybutadiene–poly(ethylene oxide) block copolymers can lead to the spontaneous formation of vesicles or membranes, which on the outside are coated with glucose and on the inside with poly(ethylene oxide).