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    Université de Fribourg

    Covalent triazine frameworks incorporating charged polypyrrole channels for high-performance lithium–sulfur batteries

    Kim, Jiheon ; Elabd, Ahmed ; Chung, Sung-Yoon ; Coskun, Ali ; Choi, Jang Wook

    In: Chemistry of Materials, 2020, vol. 32, no. 10, p. 4185–4193

    Organosulfur polymers have emerged as promising electrode materials for lithium– sulfur (Li–S) batteries, mainly because of their ability to incorporate and stabilize high sulfur content. The low ionic and electronic conductivity of these polymers, however, limit their cycling performance at high active mass loadings. Moreover, Li–polysulfide (Li–PS) shuttling, a fatal phenomenon in...

    Université de Fribourg

    Perfluoroaryl‐elemental sulfur SNAr chemistry in covalent triazine frameworks with high sulfur contents for lithium–sulfur batteries

    Je, Sang Hyun ; Kim, Hyeon Jin ; Kim, Jiheon ; Choi, Jang Wook ; Coskun, Ali

    In: Advanced Functional Materials, 2017, vol. 27, no. 47, p. -

    In order to address the challenges associated with lithium–sulfur batteries with high energy densities, various approaches, including advanced designs of sulfur composites, electrolyte engineering, and functional separators, are lately introduced. However, most approaches are effective for sulfur cathodes with limited sulfur contents, i.e., <80 wt%, imposing a significant barrier in...

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