In: Journal of the American Chemical Society, 2014, vol. 136, no. 29, p. 10493-10498
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In: RSC Advances, 2014, vol. 4, p. 53967-53974
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In: RSC Advances, 2014, vol. 4, p. 53967-53974
Many hydrocarbon polymers containing heteroatom defects in the main chain have been investigated as degradable polyethylene-like materials, including aliphatic polyesters. Here, acyclic diene metathesis (ADMET) polymerization was used for the synthesis of aliphatic poly(sulfonate ester)s. The requisite sulfonate ester containing α,ω-diene monomers with varying numbers of methylene groups...
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In: Chemistry - A European Journal, 2016, vol. 22, no. 13, p. 4374–4378
Multiresponsive materials that display predefined photoluminescence color changes upon exposure to different stimuli are attractive candidates for advanced sensing schemes. Herein, we report a cyano-substituted oligo(p-phenylene vinylene) (cyano-OPV) derivative that forms five different solvent-free solid-state molecular assemblies, luminescence properties of which change upon thermal and...
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In: ACS Appl. Mater. Interfaces, 2015, vol. 7, no. 39, p. 21828–21834
The visualization of polymer deformation using microcapsules filled with charge- transfer complex precursors is reported. Poly(urea-formaldehyde) microcapsules filled with toluene and either hexamethylbenzene as donor or chloranil as acceptor were prepared by in situ polymerization of an oil-in-water emulsion. The resulting microcapsules were incorporated in a poly(dimethylsiloxane) matrix by...
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