In: Journal of Structural Chemistry, 2011, vol. 52, no. 1, p. 151-159
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Thèse de doctorat : Université de Neuchâtel, 2015.
The self-assembly process is a natural phenomenon with the ability to organize biological systems. Its development by chemists as a synthetic process allowed the formation of esthetical structures as well as highly complex supramolecular systems with remarkable biological functions. Since 1990, metal directed self-assembly strategy has largely contributed to the design and synthesis of discrete...
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Thèse de doctorat : Université de Neuchâtel, 2012.
Depuis plusieurs années, la thérapie photo-dynamique est pratiquée au quotidien pour soigner certaines tumeurs, comme le mélanome. La méthode consiste à traiter le patient au moyen d’un composé photosensible, indifféremment absorbé par les cellules normales et cancéreuses, ces dernières le retenant toutefois plus longtemps. Après plusieurs heures, le composé est activé par une...
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In: Journal of Structural Chemistry, 2011, vol. 52, no. 1, p. 151-159
The thermal reaction of Ru3(CO)12 with the saturated fatty acids (heptanoic, nonanoic, decanoic, tridecanoic, tetradecanoic, heptadecanoic, octadecanoic) in refluxing tetrahydrofuran, followed by addition of triphenylphosphine (PPh3) or pyridine (C5H5N), gives the dinuclear complexes...
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Thèse de doctorat : Université de Neuchâtel, 2011 ; 2192.
Since the development of supramolecular chemistry in the 1980s more and more discrete molecular objects have been synthesised. In this research area metals play a key role. Indeed, the coordination-driven self-assembly allows a directional-bonding approach that organises the different building blocks into supramolecular objects according to the coordination modes of the transition metal....
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In: Polyhedron, 2007, vol. 26, no. 15, p. 4065-4072
The mononuclear cations of the general formula [(η6-arene)RuCl(dpqMe2)]+ (dpqMe2 = 6,7-dimethyl-2,3-di(pyridine-2-yl)quinoxaline; arene = C6H6, 1; C6H5Me, 2; p-PriC6H4Me, 3; C6Me6, 4) as well as the dinuclear...
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In: Inorganica Chimica Acta, 2006, vol. 359, no. 1, p. 3412-3416
The thermal reaction of Ru3(CO)12 with the biologically active acids acetyl salicylic acid (Aspirin), α-methyl-4-(isobutyl)phenylacetic acid (Ibuprofen) and 3α,7α,12α-trihydroxy-5β-cholanic acid (cholic acid) in refluxing tetrahydrofuran, followed by addition of triphenylphosphine, gives the dinuclear complexes Ru2 (CO)...
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In: Inorganica Chimica Acta, 2006, vol. 359, no. 13, p. 4350-4354
The dinuclear arene ruthenium complexes [RuCl2{C6H5(CH2)3OCO-p-C6H4-OC8H17}]2 (1) and [RuCl2{p-C6H4(CH2COOCH2CH3)2}]2 (2) have been obtained by dehydrogenation of the...
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In: Inorganica Chimica Acta, 2007, vol. 360, no. 6, p. 2023-2028
The ferrocenyl-containing diruthenium complexes [Ru2(CO)4(μ2-η2-OOCFc)2L2] (Fc = ferrocenyl, fc = ferrocen-1,1′-diyl; 1: L = NC5H4–COOC6H4–OC10H21, 2: L =...
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