Université de Neuchâtel

A Surprising Reaction of Trimethylphosphane with the Unsaturated Diruthenium Complex [(η6-C6Me6)2Ru2 (μ2-H)3]+: Synthesis and Molecular Structure of the Cations [(η6-C6Me6)Ru2 (PMe3)3 (μ2-H)3]+ and [(η6-C6Me6)2Ru2 (PMe3)2(μ2-H)(H)2]+

Tschan, Mathieu J.-L. ; Chérioux, Frédéric ; Therrien, Bruno ; Süss-Fink, Georg

In: European Journal of Inorganic Chemistry, 2007, vol. 4, p. 509-513

Whereas aromatic or aliphatic phosphanes undergo cleavage of the P-C bond in the reaction with [(η6-C6Me6)2Ru2 (μ2-H)3]+ to give phosphido-bridged diruthenium cations of the type [(η6-...

Université de Neuchâtel

Cationic arene ruthenium complexes containing chelating 1,10-phenanthroline ligands

Canivet, Jérôme ; Karmazin-Brelot, Lydia ; Süss-Fink, Georg

In: Journal of Organometallic Chemistry, 2005, vol. 690, p. 3202-3211

The monocationic chloro complexes containing chelating 1,10-phenanthroline (phen) ligands [(arene)Ru(N∩N)Cl] + (1: arene = C6H6, N∩N = phen; 2: arene = C6H6, N∩N = 5-NO2-phen; 3: arene = p-MeC6H4Pri, N∩N = phen; 4: arene =...