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Université de Neuchâtel

Photochemical [2+2] cycloaddition of the olefinic double bonds in the supramolecular rectangle [Ru4(η6-p-cymene)4(μ-oxalato)2(μ-4,4′-bipyridylethylene)2]4+

Barry, Nicolas P.E. ; Therrien, Bruno

In: Inorganic Chemistry Communications, 2009, vol. 12, no. 6, p. 465-468

Self-assembly of 4,4′-bipyridylethylene (bpe) bidentate connector with the dinuclear arene ruthenium clip [Ru2(η6-p-cymene)2(μ-oxalato)Cl2] in the presence of silver triflate affords the cationic organometallic rectangle [Ru4(η6-p-cymene)4(μ-oxalato)2(μ-bpe)2]4+...

Université de Neuchâtel

An asymmetric trihydrido-bridged arene ruthenium complex

Vieille-Petit, Ludovic ; Therrien, Bruno ; Süss-Fink, Georg

In: Inorganic Chemistry Communications, 2004, vol. 7, no. 2, p. 232-234

Reaction of [Ru(η6-indane)(H2O)3]2+ and [Ru(η6-C6Me6)(H2O)3]2+ with NaBH4 in water gives a mixture of three triple hydrido-bridged arene ruthenium cations [(η6-arene)Ru(μ-H)3Ru(η6-arene′)]+ (arene=indane and hexamethylbenzene;...