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Université de Fribourg

Supramolecular agent–simulant correlations for the luminescence based detection of V-series chemical warfare agents with trivalent lanthanide complexes

Dennison, Genevieve H. ; Bochet, Christian G. ; Curty, Christophe ; Ducry, Julien ; Nielsen, David J. ; Sambrook, Mark R. ; Zaugg, Andreas ; Johnston, Martin R.

In: European Journal of Inorganic Chemistry, 2016, p. -

Solution spectroscopic investigations into the interactions of eight potential bidentate V-series organophosphorus chemical warfare agent (OP CWA) simulants with [Eu(phen)₂(NO₃)₃]·2H₂O demonstrated that the chemical and structural composition of the secondary binding site within the simulant was of paramount importance. Only simulants containing both phosphoryl/phosphonyl and...