Ergebnisse einschränken

Ruthenium Nanoparticles Intercalated in Hectorite: A Reusable Hydrogenation Catalyst for Benzene and Toluene

Süss-Fink, Georg ; Mollwitz, Birgit ; Therrien, Bruno ; Dadras, Massoud ; Laurenczy, Gabor ; Meister, Annette ; Meister, Götz

In: Journal of Cluster Science, 2007, vol. 18, no. 1, p. 87-95

Ruthenium Nanoparticles Intercalated in Hectorite: A Reusable Hydrogenation Catalyst for Benzene and Toluene

Süss-Fink, Georg ; Mollwitz, Birgit ; Therrien, Bruno ; Dadras, Massoud ; Laurenczy, Gabor ; Meister, Annette ; Meister, Götz

In: Journal of Cluster Science, 2007, vol. 18, no. 1, p. 87-95

The cationic organometallic aqua complexes formed by hydrolysis of [(C6H6)RuCl2]2 in water, mainly [(C6H6)Ru(H2O)3]2+, intercalate into sodium hectorite by ion exchange, replacing the sodium cations between the anionic silicate layers. The yellow hectorite thus obtained reacts in ethanol with...

Mechanistic in situ High-Pressure NMR Studies of Benzene Hydrogenation by Supramolecular Cluster Catalysis with [(η6-C6H6)(η6-C6Me6)2Ru3(μ3-O)(μ2-OH)(μ2-H)2][BF4]

Laurenczy, Gabor ; Faure, Matthieu ; Vieille-Petit, Ludovic ; Süss-Fink, Georg ; Ward, Thomas R.

In: Advanced Synthesis & Catalysis, 2002, vol. 344, p. 1073-1077

In situ high-pressure NMR spectroscopy of the hydrogenation of benzene to give cyclohexane, catalysed by the cluster cation [(η6-C6H6)(η6-C6Me6)2Ru3(μ3-O)(μ2-OH)(μ2-H)2]+2, supports a mechanism involving a supramolecular host-guest...