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Ru2(CO)4{OOC(CH2) n CH3}2L2 sawhorse-type complexes containing μ2-η2-carboxylato ligands derived from saturated fatty acids

Johnpeter, J. ; Therrien, B.

In: Journal of Structural Chemistry, 2011, vol. 52, no. 1, p. 151-159

Remarkable Anticancer Activity of Triruthenium-Arene Clusters Compared to Tetraruthenium-Arene Clusters

Therrien, Bruno ; Ang, Wee ; Chérioux, Frédéric ; Vieille-Petit, Ludovic ; Juillerat-Jeanneret, Lucienne ; Süss-Fink, Georg ; Dyson, Paul

In: Journal of Cluster Science, 2007, vol. 18, no. 3, p. 741-752

Synthesis and characterization of fullerene-pyridyl arene ruthenium complexes

Appavoo, Divambal ; Deschenaux, Robert ; Therrien, Bruno

In: Studia Universitatis Babes-Bolyai. Chemia, 2015, vol. 60, no. 4, p. 229-238

Association of [60]fullerene with arene ruthenium moieties has been achieved for the first time. Two fullerenopyrrolidine derivatives (Npyr-C60) were synthesized via a 1,3-dipolar cycloaddition, and coordinated to arene ruthenium complexes to form two half-sandwich complexes of the general formula...

Tandem ring‐opening–ring‐closing metathesis for functional metathesis catalysts

Nagarkar, Amit A. ; Yasir, Mohammad ; Crochet, Aurelien ; Fromm, Katharina M. ; Kilbinger, Andreas F. M.

In: Angewandte Chemie International Edition, 2016, vol. 55, no. 40, p. 12343–12346

Use of a tandem ring-opening–ring-closing metathesis (RORCM) strategy for the synthesis of functional metathesis catalysts is reported. Ring opening of 7-substituted norbornenes and subsequent ring-closing metathesis forming a thermodynamically stable 6-membered ring lead to a very efficient synthesis of new catalysts from commercially available Grubbs’ catalysts. Hydroxy functionalized...

Efficient electronic communication of two ruthenium centers through a rigid ditopic N-heterocyclic carbene linker

Nussbaum, Michael ; Schuster, Oliver ; Albrecht, Martin

In: Chemistry – A European Journal, 2013, vol. 19, no. 51, p. 17517–17527

A ditopic benzobis(carbene) ligand precursor was prepared that contained a chelating pyridyl moiety to ensure co-planarity of the carbene ligand and the coordination plane of a bound octahedral metal center. Bimetallic ruthenium complexes comprising this ditopic ligand [L₄Ru-C,N-bbi-C,N-RuL₄] were obtained by a transmetalation methodology...

Evidence for Drug Release from a Metalla-Cage Delivery Vector Following Cellular Internalisation

Zava, Olivier ; Mattsson, Johan ; Therrien, Bruno ; Dyson, Paul J.

In: Chemistry - A European Journal, 2010, vol. 16, no. 5, p. 1428–1431

Excellent Correlation between Drug Release and Portal Size in Metalla-Cage Drug-Delivery Systems

Barry, Nicolas P.E. ; Zava, Olivier ; Dyson, Paul J. ; Therrien, Bruno

In: Chemistry - A European Journal, 2011, vol. 17, no. 35, p. 9669-9677

A series of large cationic hexanuclear metalla-prisms, [Ru6(p-iPrC6H4Me)6(tpt)2(donq)3]6+, [Ru6(p-iPrC6H4Me)6(tpt)2(doaq)3]6+ and...

Ru2(CO)4{OOC(CH2)nCH3}2L2 sawhorse-type complexes containing μ2-η2-carboxylato ligands derived from saturated fatty acids

Johnpeter, J. P. ; Therrien, Bruno

In: Journal of Structural Chemistry, 2011, vol. 52, no. 1, p. 151-159

The thermal reaction of Ru3(CO)12 with the saturated fatty acids (heptanoic, nonanoic, decanoic, tridecanoic, tetradecanoic, heptadecanoic, octadecanoic) in refluxing tetrahydrofuran, followed by addition of triphenylphosphine (PPh3) or pyridine (C5H5N), gives the dinuclear complexes...

Water Oxidation: A Robust All-Inorganic Catalyst

Süss-Fink, Georg

In: Angewandte Chemie International Edition, 2008, vol. 47, no. 32, p. 5888-5890

The Complex-in-a-Complex Cations [(acac)2M⊂Ru6(p-iPrC6H4Me)6(tpt)2 (dhbq)3]6+: A Trojan Horse for Cancer Cells

Therrien, Bruno ; Süss-Fink, Georg ; Govindaswamy, Padavattan ; Renfrew, Anna K. ; Dyson, Paul J.

In: Angewandte Chemie International Edition, 2008, vol. 47, no. 20, p. 3773-3776