In: European Journal of Inorganic Chemistry, 2012, p. -
Heterobimetallic lithium–iron coordination compounds are interesting targets for several reasons: they can be used as precursors for mixed metal oxides, as catalysts, for example, for ring-opening polymerization reactions or to study oxidation/reduction processes. Finally their magnetic properties are also of interest. New heterobimetallic aryloxide complexes, namely...
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In: European Journal of Inorganic Chemistry, 2010, no. 5, p. 675-679
Thermal spin crossover (SCO) was induced in a high-spin FeIII complex by alkylation of the polyamino ligand backbone. The SCO profile was responsive to chain length with partial crossover observed with C₆ alkylation and full transition upon lengthening to C₁₂. No crossover was observed when the backbone was unfunctionalised, and all three complexes were obtained as unsolvated...
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