Université de Neuchâtel

Dinuclear hexamethylbenzene ruthenium cations containing η1:η2-2-(ferrocenyl)ethen-1-yl ligands: Synthesis, structure, electrochemistry

Tschan, Mathieu J.-L. ; Therrien, Bruno ; Ludvík, Jiří ; Štěpnička, Petr ; Süss-Fink, Georg

In: Journal of Organometallic Chemistry, 2006, vol. 691, no. 20, p. 4304-4311

The cationic ferrocenyl-containing complexes [(η6-C6Me6)2Ru2 (μ-η1:η2-CH–CHFc)2 (μ-H)]+ (3) and [(η6-C6Me6)2Ru2 (μ-PPh2)(μ-η1:η2-CH–CHFc)(μ-H)]+ (4) have been synthesised in ethanol...

Université de Neuchâtel

Mono and dinuclear rhodium, iridium and ruthenium complexes containing chelating 2,2′-bipyrimidine ligands: Synthesis, molecular structure, electrochemistry and catalytic properties

Govindaswamy, Padavattan ; Canivet, Jérôme ; Therrien, Bruno ; Süss-Fink, Georg ; Štěpnička, Petr ; Ludvík, Jiří

In: Journal of Organometallic Chemistry, 2007, vol. 692, no. 17, p. 3664-3675

The mononuclear cations [(η5-C5Me5)RhCl(bpym)]+ (1), [(η5-C5Me5)IrCl(bpym)]+ (2), [(η6-p-PriC6H4Me)RuCl(bpym)]+ (3) and [(η6-C6Me6)RuCl(bpym)]+ (4) as well as the dinuclear dications...

Université de Neuchâtel

Synthesis, structure and electrochemistry of cationic diruthenium complexes of the type [(N∩N)2Ru2 (CO)2 (μ-CO)2(μ-OOCFc)]+ containing a ferrocenecarboxylato bridge and two chelating aromatic diimine ligands

Auzias, Mathieu ; Therrien, Bruno ; Süss-Fink, Georg ; Štěpnička, Petr ; Ludvík, Jiří

In: Journal of Organometallic Chemistry, 2007, vol. 692, no. 4, p. 755-760

The dinuclear bis(ferrocenecarboxylato) complex Ru2 (CO)4 (μ-OOCFc)2 (py)2 (Fc = ferrocenyl, py = pyridine) was found to react with aromatic diimines (2,2′-dipyridyl, 4,4′-dimethyl-2,2′-dipyridyl, 1,10-phenanthroline, 5-nitro-1,10-phenanthroline, and 5-amino-1,10-phenanthroline) in methanol to give the cationic diruthenium complexes...

Université de Neuchâtel

Mono and dinuclear iridium, rhodium and ruthenium complexes containing chelating carboxylato pyrazine ligands: Synthesis, molecular structure and electrochemistry

Govindaswamy, Padavattan ; Therrien, Bruno ; Süss-Fink, Georg ; Štěpnička, Petr ; Ludvík, Jiří

In: Journal of Organometallic Chemistry, 2007, vol. 692, no. 8, p. 1661-1671

The mononuclear complexes [(η5-C5Me5)IrCl(L1)] (1), [(η5-C5Me5)RhCl(L1)] (2), [(η6-p-PriC6H4Me)RuCl(L1)] (3) and [(η6-C6Me6)RuCl(L1)] (4) have been synthesised from...