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Organometallic boxes built from 5,10,15,20-tetra(4-pyridyl)porphyrin panels and hydroxyquinonato-bridged diruthenium clips

Barry, Nicolas P.E. ; Govindaswamy, Padavattan ; Furrer, Julien ; Süss-Fink, Georg ; Therrien, Bruno

In: Inorganic Chemistry Communications, 2008, vol. 11, no. 10, p. 1300-1303

Self-assembly of 5,10,15,20-tetra(4-pyridyl)porphyrin (tpp-H2) tetradentate panels with dinuclear arene ruthenium clips [Ru2 (η6-arene)2 (dhbq)Cl2] (arene = C6H5Me, p-PriC6H4Me, C6Me6; dhbq = 2,5-dihydroxy-1,4-benzoquinonato) affords the cationic organometallic boxes...

Self-assembled chloro-bridged metallo-prismatic cations of the general formula [M6 (η5-C5Me5)6 (μ3-tpt)2 (μ-Cl)6]6+ (M = Rh, Ir; tpt = 2,4,6-tri(pyridin-4-yl)-1,3,5-triazine)

Govindaswamy, Padavattan ; Süss-Fink, Georg ; Therrien, Bruno

In: Inorganic Chemistry Communications, 2007, vol. 10, no. 12, p. 1489-1492

Two cationic pentamethylcyclopentadienyl metal-based hexanuclear complexes with trigonal prismatic architecture have been synthesised through a two-step strategy. The dinuclear complexes [M(η5- C5Me5)(μ-Cl)Cl]2 (M = rhodium and iridium) react with 2,4,6-tri(pyridin-4-yl)-1,3,5-triazine (tpt) in dichloromethane to give the trinuclear complexes...

Supramolecular Cluster Catalysis : Benzene Hydrogenation Catalyzed by a Cationic Triruthenium Cluster under Biphasic Conditions

Süss-Fink, Georg ; Faure, Matthieu ; Ward, Thomas R.

In: Angewandte Chemie, International Edition, 2002, p. 99-101

The Complex-in-a-Complex Cations [(acac)2M⊂Ru6(p-iPrC6H4Me)6(tpt)2 (dhbq)3]6+: A Trojan Horse for Cancer Cells

Therrien, Bruno ; Süss-Fink, Georg ; Govindaswamy, Padavattan ; Renfrew, Anna K. ; Dyson, Paul J.

In: Angewandte Chemie International Edition, 2008, vol. 47, no. 20, p. 3773-3776