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    Université de Neuchâtel

    Liquid-Crystalline [60]Fullerene-TTF Dyads

    Allard, Emmanuel ; Oswald, Frédéric ; Donnio, Bertrand ; Guillon, Daniel ; Delgado, Juan Luis ; Langa, Fernando ; Deschenaux, Robert

    In: Organic Letters, 2005, vol. 7, no. 3, p. 383-386

    [60]Fullerene was functionalized with a TTF derivative and a bis-mesogenic fragment. The synthetic methodology was based on the addition of a malonate derivative to C60 (Bingel-type reaction). Both the malonate and dyad showed smectic B and A phases. The supramolecular organization within the smectic layers was of the monolayer type for the malonate and of the bilayer type for the...