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The Primary steps in excited-state hydrogen transfer: the phototautomerization of o-nitrobenzyl derivatives

Šolomek, Tomáš ; Bochet, Christian G. ; Bally, Thomas

In: Chemistry – A European Journal, 2014, vol. 20, no. 26, p. 8062–8067

The quantum yield for the release of leaving groups from o-nitrobenzyl “caged” compounds varies greatly with the nature of these leaving groups, for reasons that have never been well understood. We found that the barriers for the primary hydrogen-atom transfer step and the efficient nonradiative processes on the excited singlet and triplet surfaces determine the quantum yields. The...

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Photochemistry of reactive intermediates

Bally, Thomas

In: Chimia, 2007, vol. 61, no. 10, p. 645-649

This paper illustrates the research on the photochemistry of reactive intermediates that was (and still is) carried out in the author's research group on three typical examples: the photochemistry of arylcarbenes, arylnitrenes, and organic radical cations.

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