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The spectroscopy and thermochemistry of phenylallyl radical chromophores

Troy, Tyler P. ; Chalyavi, Nahid ; Menon, Ambili S. ; O'Connor, Gerard D. ; Fückel, Burkhard ; Nauta, Klaas ; Radom, Leo ; Schmidt, Timothy W.

In: Chemical Science, 2011, vol. 2, no. 9, p. 1755-1765

The resonant two-color two-photon ionization and laser induced fluorescence excitation spectra of the 1-phenylallyl (cinnamyl) and inden-2-ylmethyl radicals are reported. The 1-phenylallyl radical is found to fluoresce with low yield, permitting only a coarse dispersed fluorescence spectrum, while the inden-2-ylmethyl radical yields sufficient fluorescence to obtain ground-state vibrational...