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Radicals and radical ions as intermediates of electron transfer processes through peptides

Giese, Bernd ; Eckhardt, Sonja ; Lauz, Miriam ; Gao, Jian ; Wang, Min

In: Chimia, 2012, vol. 66, no. 6, p. 364-367

Electron transfer (ET) through peptides and proteins is a key biochemical process, which involves radicals and radical ions as reactive intermediates. We have developed an assay that allows us to study this fundamental chemical reaction.

Electron transfer in peptides: the influence of charged amino acids

Gao, Jian ; Müller, Pavel ; Wang, Min ; Eckhardt, Sonja ; Lauz, Miriam ; Fromm, Katharina M. ; Giese, Bernd

In: Angewandte Chemie International Edition, 2011, vol. 50, no. 8, p. 1926-1930