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Synthesis and characterization of fullerene-pyridyl arene ruthenium complexes

Appavoo, Divambal ; Deschenaux, Robert ; Therrien, Bruno

In: Studia Universitatis Babes-Bolyai. Chemia, 2015, vol. 60, no. 4, p. 229-238

Association of [60]fullerene with arene ruthenium moieties has been achieved for the first time. Two fullerenopyrrolidine derivatives (Npyr-C60) were synthesized via a 1,3-dipolar cycloaddition, and coordinated to arene ruthenium complexes to form two half-sandwich complexes of the general formula...