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Resolution limit of taylor dispersion: an exact theoretical study

Taladriz-Blanco, Patricia ; Rothen-Rutishauser, Barbara ; Petri-Fink, Alke ; Balog, Sandor

In: Analytical Chemistry, 2020, vol. 92, no. 1, p. 561–566

Taylor dispersion is a microfluidic analytical technique with a high dynamic range and therefore is suited well to measuring the hydrodynamic radius of small molecules, proteins, supramolecular complexes, macromolecules, nanoparticles and their self- assembly. Here we calculate an unaddressed yet fundamental property: the limit of resolution, which is defined as the smallest change in the...