Université de Fribourg

Activation mechanism and infiltration kinetic for pressureless melt infiltration of Ti activated Al₂O₃ preforms by high melting alloy

Vasi, Srdan ; Grobéty, Bernard ; Kuebler, Jakob ; Graule, Thomas

In: Advanced Engineering Materials, 2009, vol. 11, no. 8, p. 659 - 666

The infiltration mechanism of X3CrNi13-4 in titanium activated porous alumina preforms has been studied. Investigations revealed isolated steel-covered titanium particles beyond the infiltration front. The only transport path possible for the steel to form such wetted islands is through the gas phase. Supersaturation due to the mixing of the steel gas phase with the titanium rich gas phase...

Université de Fribourg

CSL grain boundary distribution in alumina and zirconia ceramics

Vonlanthen, Pierre ; Grobéty, Bernard

In: Ceramics International, 2008, vol. 34, no. 6, p. 1459-1472

The distributions of general and coincidence site lattice (CSL) grain boundaries (GBs) in texture-free alumina and zirconia ceramics sintered at two different temperatures were investigated based on electron backscatter diffraction (EBSD) measurements. Results were compared with the distributions obtained from random 2D spatial models and with calculated random distributions reported in the...

Université de Fribourg

Growth mechanism of snowball garnets from the Lukmanier Pass area (Central Alps, Switzerland): a combined μCT/EPMA/EBSD study

Robyr, Martin ; Vonlanthen, Pierre ; Baumgartner, Lukas P. ; Grobéty, Bernard

In: Terra Nova, 2007, vol. 19, no. 4, p. 240-244

For two decades, considerable efforts have been made to explain the formation of snowball garnets by either the rotational or non-rotational models. On the basis of morphological, chemical and crystallographic evidence, this paper presents new data on snowball garnets showing that the formation of these microstructures can be explained by the combination of the two previously proposed mechanisms...

Université de Fribourg

X-ray computed micro tomography as complementary method for the characterization of activated porous ceramic preforms

Vasic, Srdan ; Grobéty, Bernard ; Kuebler, J. ; Graule, T. ; Baumgartner, Lukas P.

In: Journal of Materials Research, 2007, vol. 22, no. 5, p. 1414-1424

X-ray computed micro tomography (CT) is an alternative technique to the classical methods such as mercury intrusion (MIP) and gas pycnometry (HP) to obtain the porosity, pore-size distribution, and density of porous materials. Besides the advantage of being a nondestructive method, it gives not only bulk properties, but also spatially resolved information. In the present work, uniaxially pressed...