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Université de Neuchâtel

Insight into the rules dictating the formation of arene ruthenium metalla-assemblies

Garci, Amine ; Therrien, Bruno (Dir.)

Thèse de doctorat : Université de Neuchâtel, 2015.

The self-assembly process is a natural phenomenon with the ability to organize biological systems. Its development by chemists as a synthetic process allowed the formation of esthetical structures as well as highly complex supramolecular systems with remarkable biological functions. Since 1990, metal directed self-assembly strategy has largely contributed to the design and synthesis of discrete...

Université de Neuchâtel

The Adaptable Coordination Chemistry of 6-Chloro-2-(quinolin-2-yl)-2,4-dihydro-1H-benzo[d][1,3]oxazine Towards Zinc(II) and Mercury(II)

Attilio Ardizzoia, G. ; Brenna, Stefano ; Therrien, Bruno

In: European Journal of Inorganic Chemistry, 2010, vol. 2010, no. 21, p. 3365-3371

The coordination chemistry of 6-chloro-2-(quinolin-2-yl)-2,4-dihydro-1H-benzo[d][1,3]oxazine (LH2) towards zinc and mercury has been explored. The ligand exhibits high versatility and provides different environments to the metal centre as a function of its diverse coordination modes. In one of the isolated and characterized complexes,...

Université de Fribourg

Chelating C4-bound imidazolylidene complexes through oxidative addition of imidazolium salts to palladium(0)

Krüger, Anneke ; Kluser, Evelyne ; Müller-Bunz, Helge ; Neels, Antonia ; Albrecht, Martin

In: European Journal of Inorganic Chemistry, 2012, p. -

Oxidative addition of donor-functionalised 4-iodoimidazolium salts to palladium(0) provides a selective route for the preparation of abnormal chelating N-heterocyclic carbene complexes and enables the introduction of a variety of donor groups. The activation of the C4 position does not necessitate protection of the imidazolium C2 position, thereby leaving this site available for further...

Université de Neuchâtel

Square-Planar Diacetatopalladium Complexes with trans-Configured Secondary Amine Ligands that Avoid Orthometalation: Ligand Synthesis, Coordination, Molecular Structure and Catalytic Potential for Suzuki Cross-Coupling Reactions

Chahen, Ludovic ; Therrien, Bruno ; Süss-Fink, Georg

In: European Journal of Inorganic Chemistry, 2007, vol. 32, p. 5045-5051

The trans-configured square-planar palladium complexes [Pd(OAc)2 (LNtBu)2] (1), [Pd(OAc)2 (η2-LN∩NtBu)] (2), [Pd(OAc)2 (LNPh)2] (3), and [Pd(OAc)2 (η2-LN∩NPh)] (4), have been synthesized by treating palladium acetate with the amines...

Université de Neuchâtel

Mono and dinuclear rhodium, iridium and ruthenium complexes containing chelating 2,2′-bipyrimidine ligands: Synthesis, molecular structure, electrochemistry and catalytic properties

Govindaswamy, Padavattan ; Canivet, Jérôme ; Therrien, Bruno ; Süss-Fink, Georg ; Štěpnička, Petr ; Ludvík, Jiří

In: Journal of Organometallic Chemistry, 2007, vol. 692, no. 17, p. 3664-3675

The mononuclear cations [(η5-C5Me5)RhCl(bpym)]+ (1), [(η5-C5Me5)IrCl(bpym)]+ (2), [(η6-p-PriC6H4Me)RuCl(bpym)]+ (3) and [(η6-C6Me6)RuCl(bpym)]+ (4) as well as the dinuclear dications...

Université de Neuchâtel

Self-assembled chloro-bridged metallo-prismatic cations of the general formula [M6 (η5-C5Me5)6 (μ3-tpt)2 (μ-Cl)6]6+ (M = Rh, Ir; tpt = 2,4,6-tri(pyridin-4-yl)-1,3,5-triazine)

Govindaswamy, Padavattan ; Süss-Fink, Georg ; Therrien, Bruno

In: Inorganic Chemistry Communications, 2007, vol. 10, no. 12, p. 1489-1492

Two cationic pentamethylcyclopentadienyl metal-based hexanuclear complexes with trigonal prismatic architecture have been synthesised through a two-step strategy. The dinuclear complexes [M(η5- C5Me5)(μ-Cl)Cl]2 (M = rhodium and iridium) react with 2,4,6-tri(pyridin-4-yl)-1,3,5-triazine (tpt) in dichloromethane to give the trinuclear complexes...

Université de Neuchâtel

Mono and dinuclear arene ruthenium complexes containing 6,7-dimethyl-2,3-di(pyridine-2-yl)quinoxaline as chelating ligand: Synthesis and molecular structure

Therrien, Bruno ; Süss-Fink, Georg ; Govindaswamy, Padavattan ; Saïd-Mohamed, Cynthia

In: Polyhedron, 2007, vol. 26, no. 15, p. 4065-4072

The mononuclear cations of the general formula [(η6-arene)RuCl(dpqMe2)]+ (dpqMe2 = 6,7-dimethyl-2,3-di(pyridine-2-yl)quinoxaline; arene = C6H6, 1; C6H5Me, 2; p-PriC6H4Me, 3; C6Me6, 4) as well as the dinuclear...

Université de Fribourg

Polytopal rearrangement of [Ni(acac)₂(py)]: A new square pyramid ⇄ trigonal bipyramid twist mechanism

Daul, Claude ; Niketic, Svetozar ; Rauzy, Cédrick ; Schläpfer, Carl-Wilhelm

In: Chemistry - A European Journal, 2004, vol. 10(3), p. 721-727

The interconversion mechanisms between three idealized polytopal forms (a square pyramid and two trigonal bipyramids) of [M(bidentate)₂(unidentate)] were investigated by an original combination of molecular mechanics (MM) and density functional theory (DFT) approaches. MM was used to model the mechanistic rearrangement path, and DFT to study selected points along this path. The test case was a...