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Synthesis and application of an electronically chiral mimic of CpFe

Allemann, Christophe ; Jenny, Titus (Dir.)

Thèse de doctorat : Université de Fribourg, 2002 ; No 1369.

The field of new optically active and reactive organometallic species is of tremendous interest. Within this area, (-)-(1S)-dicarbonyliodide[μ5-(2,8,8-tri-methylbicyclo[3.2.1]oct-3,6-diene)2-yl] iron (1), called 2-Me-BOD-Fe(CO)2I, emerges as a new stage in the development of chiral cyclopentadienyl-like complexes. Studying the reactivity of 1 has shown that both its non-contiguous μ5-system and...