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New ruthenium(II) complexes with enantiomerically pure bis- and tris(pinene)-fused tridentate ligands: synthesis, characterization and stereoisomeric analysis

Sala, Xavier ; Poater, Albert ; Zelewsky, Alexander von ; Parella, Teodor ; Fontrodona, Xavier ; Romero, Isabel ; Solà, Miquel ; Rodríguez, Montserrat ; Llobet, Antoni

In: Inorganic Chemistry, 2008, vol. 47, no. 18, p. 8016–8024

A new set of Ru−Cl complexes containing either the pinene[5,6]bpea ligand (L1) or the C₃ symmetric pinene[4,5]tpmOMe (L2) tridentate ligand in combination with the bidentate (B) 2,2′-bipyridine (bpy) or 1,2-diphenylphosphinoethane (dppe) with general formula [RuCl(L1 or L2)(B)]⁺ have been prepared and thoroughly characterized. In the solid state, X-ray diffraction...