In: Zeitschrift für anorganische und allgemeine Chemie, 2012, vol. 638, no. 11, p. 1810–1819
New homoligand and mixed-ligand adducts of the heavier alkaline earth metal (Ca, Sr, Ba) halides with oxygen-donor polyether ligands have been isolated and characterized and are compared with previously obtained compounds of the same class in order to give an overview on structures and properties. Homoligand halide adducts, discussed herein, are [CaI(DME)₃]I (1),...
|
In: CHIMIA International Journal for Chemistry, 2010, vol. 64, no. 5, p. 299-320
Heterometallic oxides are used as materials in many applications, e.g. from ferroelectrics to superconductors. Making these compounds usually requires high temperatures and long reaction times. Molecular precursors may contribute to render their processing shorter and accessible at lower temperatures, thus cheaper in energy and time. In this review article, different approaches toward oxide...
|
In: Helvetica Chimica Acta, 2009, vol. 92, no. 11, p. 2349-2356
Two new heterobimetallic phenoxide LnIII-Li complexes of formula [Ln(μ₂-OPh)₆{Li(dme)}₃] (Ln=Sm, Eu) have been synthesized and characterized using single-crystal X-ray diffraction. These two compounds are isostructural.
|
In: Chemistry - A European Journal, 2007, vol. 13, no. 29, p. 8302 - 8316
As previously shown, alkali and alkaline earth metal iodides in nonaqueous, aprotic solvents behave like transition metal halides, forming cis- and trans-dihalides with various neutral O-donor ligands. These compounds can be used as precursors for the synthesis of new mixed alkali/alkaline earth metal aggregates. We show here that Ln²⁺ ions form isostructural cluster compounds....
|