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Université de Fribourg

A petunia chorismate mutase specialized for the production of floral volatiles

Colquhoun, Thomas A. ; Schimmel, Bernardus C.J. ; Kim, Joo Young ; Reinhardt, Didier ; Cline, Kenneth ; Clark, David G.

In: The Plant Journal, 2010, vol. 61, no. 1, p. 145-155

In Petunia × hybrida cv. 'Mitchell Diploid' floral fragrance is comprised of 13 volatile benzenoids/phenylpropanoids derived from the aromatic amino acid phenylalanine. Several genes involved in the direct synthesis of individual floral volatile benzenoid/phenylpropanoid (FVBP) compounds, i.e. at the end of the pathway, have been isolated and characterized in petunia through reverse genetic and...

Université de Fribourg

Arabidopsis thaliana class-II TGA transcription factors are essential activators of jasmonic acid/ethylene-induced defense responses

Zander, Mark ; Camera, Sylvain La ; Lamotte, Olivier ; Métraux, Jean-Pierre ; Gatz, Christiane

In: The Plant Journal, 2010, vol. 61, no. 2, p. 200 - 210

The three closely related Arabidopsis basic leucine zipper (bZIP) transcription factors TGA2, TGA5 and TGA6 are required for the establishment of the salicylic acid (SA)-dependent plant defense response systemic acquired resistance, which is effective against biotrophic pathogens. Here we show that the same transcription factors are essential for the activation of jasmonic acid (JA)- and ethylene...

Université de Fribourg

Water limitation prevails over energy in European diversity gradients of sheetweb spiders (Araneae: Linyphiidae)

Kumschick, Sabrina ; Schmidt-Entling, Martin H. ; Bacher, Sven ; Hickler, Thomas ; Entling, Wiebke ; Nentwig, Wolfgang

In: Basic and Applied Ecology, 2009, vol. 10, no. 8, p. 754-762

Across large spatial scales, species richness in many taxa is mainly determined by climatic variables. However, some of the mechanisms behind large-scale patterns of species richness and abundance are expected to act on the community level, and on a smaller scale than the resolution of the data commonly used for deriving these patterns. We studied the distribution of sheetweb spiders (Araneae:...

Université de Fribourg

A new instrument for time-resolved static and dynamic light-scattering experiments in turbid media

Moitzi, Christian ; Vavrin, Ronny ; Bhat, Suresh Kumar ; Stradner, Anna ; Schurtenberger, Peter

In: Journal of Colloid and Interface Science, 2009, vol. 336, no. 2, p. 565-574

We present a new 3D cross-correlation instrument that not only allows for static and dynamic scattering experiments with turbid samples but measures at four angles simultaneously. It thus extends the application of cross-correlation light scattering to time-resolved studies where we can, for example, efficiently investigate the temporal evolution of aggregating or phase separating turbid...

Université de Fribourg

Light scattering near and from interfaces using evanescent wave and ellipsometric light scattering

Sigel, Reinhard

In: Current Opinion in Colloid & Interface Science, 2009, vol. 14, no. 6, p. 426-437

The broad range of interface light scattering investigations in recent years shows the power and the versatility of these techniques to address new and open questions in colloid and interface science and the soft condensed matter field. Structural information for polymers, liquid crystals, or colloids close to planar or spherical colloidal interfaces are either captured with long range light...

Université de Fribourg

Influence of temperature on low-power upconversion in rubbery polymer blends

Singh-Rachford, Tanya N. ; Lott, Joseph ; Weder, Christoph ; Castellano, Felix N.

In: Journal of the American Chemical Society, 2009, vol. 131, no. 33, p. 12007–12014

The upconverting properties of a dye cocktail composed of palladium(II) octaethylporphyrin (PdOEP, triplet sensitizer) and 9,10-diphenylanthracene (DPA, triplet acceptor/annihilator) were investigated as a function of temperature in several low glass transition temperature (Tg) polymer hosts including an ethyleneoxide-epichlorohydrin copolymer (EO-EPI) and the polyurethanes...

Université de Fribourg

Separation of coherent and incoherent scattering contributions in ellipsometric light scattering experiments on latex mixtures

Erbe, Andreas ; Tauer, Klaus ; Sigel, Reinhard

In: Langmuir, 2009, vol. 25, no. 5, p. 2703–2710

Mixtures of poly(styrene) latices were used to vary the sample polydispersity for an investigation of polydispersity effects on ellipsometric light scattering (ELS) data. A procedure for high-accuracy ELS measurements is presented and the experimental distinction of coherent and incoherent scattering contributions is demonstrated. The ellipsometric parameters tan(ΨQ) and Δ are solely...

Université de Fribourg

Photoinitiated coupling of unmodified monosaccharides to iron oxide nanoparticles for sensing proteins and bacteria

Liu, Li-Hong ; Dietsch, Hervé ; Schurtenberger, Peter ; Yan, Mingdi

In: Bioconjugate Chemistry, 2009, vol. 20, no. 7, p. 1349–1355

We report a versatile approach for the immobilization of unmodified monosaccharides onto iron oxide nanoparticles. Covalent coupling of the carbohydrate onto iron oxide nanoparticle surfaces was accomplished by the CH insertion reaction of photochemically activated phosphate-functionalized perfluorophenylazides (PFPAs), and the resulting glyconanoparticles were characterized by IR, TGA, and TEM....

Université de Fribourg

Synthesis and self-assembly behavior of poly(fluorenylstyrene)-block-poly(2-vinylpyridine) block copolymers and their blends with single wall carbon nanotubes (SWCNTs)

Li, Chaoxu ; Hsu, Jung-Ching ; Sugiyama, Kenji ; Hirao, Akira ; Chen, Wen-Chang ; Mezzenga, Raffaele

In: Macromolecules, 2009, vol. 42, no. 15, p. 5793–5801

We have synthesized a series of poly[4-(9,9-dihexylfluoren-2-yl)styrene]-block-poly(2-vinylpyridine) (P(St-F1)-b-P2VP) and poly[4-di(9,9-dihexylfluoren-2-yl)styrene]-block-poly(2-vinylpyridine) (P(St-F1₂)-b-P2VP) comblike block copolymers and investigated their self-assembly behavior. The block composition, molecular weight, and the length of the fluorene side chain...