In: Science Advances, 2017, vol. 3, no. 10, p. e1700969
Tuning the solubility of fuzzy polymer microgels by external triggers, such as temperature or pH, provides a unique mechanism for controlling the porosity and size of colloidal particles on the nanoscale. As a consequence, these smart microgel particles are being considered for applications ranging from viscosity modifiers and sensing to drug delivery and as models for the glass and the...
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In: Nanoscale, 2017, vol. 9, no. 38, p. 14405-14413
We describe the synthesis of hybrid magnetic ellipsoidal nanoparticles that consist of a mixture of two different iron oxide phases, hematite (α-Fe2O3) and maghemite (γ- Fe2O3), and characterize their magnetic field-driven self-assembly. We demonstrate that the relative amount of the two phases can be adjusted in a continuous way by varying the reaction time during the synthesis, leading to...
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In: Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2016, vol. 499, p. 18–23
Hierarchical polymer structures such as pNIPAM microgels have been extensively studied for their ability to undergo structural and physical transformations that can be controlled by external stimuli such as temperature, pH or solvent composition. However, a direct three-dimensional visualization of individual particles in-situ has so far been hindered by insufficient resolution, with optical...
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In: Nanoscale, 2015, p. -
Light scattering is one of the few techniques available to adequately characterize suspended nanoparticles (NPs) in real time and in situ. However, when it comes to NPs in multicomponent and optically complex aqueous matrices – such as biological media and physiological fluids – light scattering suffers from lack of selectivity, as distinguishing the relevant optical signals from the...
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In: Proceedings of the National Academy of Sciences, 2014, vol. 111, no. 47, p. 16748–16753
We study the equilibrium liquid structure and dynamics of dilute and concentrated bovine eye lens α-crystallin solutions, using small-angle X-ray scattering, static and dynamic light scattering, viscometry, molecular dynamics simulations, and mode-coupling theory. We find that a polydisperse Percus–Yevick hard-sphere liquid-structure model accurately reproduces both static light scattering...
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In: The Journal of Physical Chemistry C, 2014, vol. 118, no. 31, p. 17968–17974
Although small round gold nanoparticles (Au NPs) possess only a small degree of shape anisotropy, they support localized surface plasmon resonances and exhibit intrinsic optical anisotropy. These inherent features promote depolarized light scattering, whose temporal fluctuations carry information about rotational Brownian dynamics, and thus can be used to describe the size distribution of...
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In: Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2014, vol. 445, p. 21-29
We have synthesized hematite cube-shaped nanoparticles using different synthesis paths to examine the effect of the intermediate product akaganeite (β-FeOOH) on the size and shape of the final hematite particles. Akaganeite spindles and hematite nanocubes are prepared using forced hydrolysis of iron chloride (FeCl₃) salt. We use a combination of transmission electron microscopy (TEM), high...
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In: The Journal of Chemical Physics, 2014, vol. 140, no. 9, p. 094901
We describe a combined experimental, theoretical, and simulation study of the structural correlations between cross-linked highly monodisperse and swollen Poly(N-isopropylacrylamide) microgel dispersions in the fluid phase in order to obtain the effective pair-interaction potential between the microgels. The density-dependent experimental pair distribution functions g(r)’s are deduced from real...
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In: Physical Review Letters, 2013, vol. 110, no. 5, p. 058303
We show that gels formed by arrested spinodal decomposition of protein solutions exhibit elastic properties in two distinct frequency domains, both elastic moduli exhibiting a remarkably strong dependence on volume fraction. Considering the large difference between the protein size and the characteristic length of the network we model the gels as porous media and show that the high and low...
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In: Soft MatterSoft Matter, 2012, vol. 8, no. 42, p. 10819-10822
Ionic microgels are intriguing soft and deformable colloids with an effective pair potential that crosses over from Yukawa-like at large distances to a much softer repulsive interaction at short distances. Here we report the effect of adding an anisotropic dipolar contribution to colloids with such “ultra-soft” interactions. We use an alternating electric field to induce a tunable dipolar...
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