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Université de Fribourg

Metallic contact between MoS2 and Ni via Au nanoglue

Shi, Xinying ; Posysaev, Sergei ; Huttula, Marko ; Pankratov, Vladimir ; Hoszowska, Joanna ; Dousse, Jean-Claude ; Zeeshan, Faisal ; Niu, Yuran ; Zakharov, Alexei ; Li, Taohai ; Miroshnichenko, Olga ; Zhang, Meng ; Wang, Xiao ; Huang, Zhongjia ; Saukko, Sami ; González, Diego López ; Dijken, Sebastiaan van ; Alatalo, Matti ; Cao, Wei

In: Small, 2018, vol. 14, no. 22, p. 1704526

A critical factor for electronics based on inorganic layered crystals stems from the electrical contact mode between the semiconducting crystals and the metal counterparts in the electric circuit. Here, a materials tailoring strategy via nanocomposite decoration is carried out to reach metallic contact between MoS2 matrix and transition metal nanoparticles. Nickel nanoparticles (NiNPs) are ...

Université de Fribourg

Double K-shell photoionization and hypersatellite x-ray transitions of 12⩽Z⩽23 atoms

Hoszowska, Joanna ; Dousse, Jean-Claude ; Cao, Wei ; Fennane, Karima ; Kayser, Yves ; Szlachetko, Monika ; Szlachetko, Jakub ; Kavčič, Matjaz

In: Physical Review A, 2010, vol. 82, no. 6, p. 063408

Single-photon double K-shell ionization of low-Z neutral atoms in the range 12⩽Z⩽23 is investigated. The experimental method was based on measurements of the high- resolution Kαh hypersatellite x-ray spectra following the radiative decay of the K-shell double-vacancy states excited by monochromatic synchrotron radiation. The photon energy dependence of the double K-shell ionization was...

Université de Fribourg

Vacuum ultraviolet excitation luminescence spectroscopy of few-layered MoS 2

Pankratov, V ; Hoszowska, Joanna ; Dousse, Jean-Claude ; Huttula, M ; Kis, A ; Krasnozhon, D ; Zhang, M ; Cao, Wei

In: Journal of Physics: Condensed Matter, 2016, vol. 28, no. 1, p. 015301

We report on vacuum ultraviolet (VUV) excited photoluminescence (PL) spectra emitted from a chemical vapor deposited MoS₂ few-layered film. The excitation spectrum was recorded by monitoring intensities of PL spectra at ~1.9 eV. A strong wide excitation band peaking at 7 eV was found in the excitation. The PL excitation band is most intensive at liquid helium temperature and completely...

Université de Fribourg

High-energy-resolution grazing emission X-ray fluorescence applied to the characterization of thin Al films on Si

Kayser, Yves ; Szlachetko, Jakub ; Banaś, D. ; Cao, Wei ; Dousse, Jean-Claude ; Hoszowska, Joanna ; Kubala-Kukuś, A. ; Pajek, M.

In: Spectrochimica Acta Part B: Atomic Spectroscopy, 2014, vol. 88, p. 136-149

The grazing emission X-ray fluorescence (GEXRF) technique was applied to the analysis of different Al films, with nominal thicknesses in the range of 1 nm to 150 nm, on Si wafers. In GEXRF the sample volume from which the fluorescence intensity is detected is restricted to a near-surface region whose thickness can be tuned by varying the observation angle. This is possible because of the...

Université de Fribourg

Grazing angle X-ray fluorescence from periodic structures on silicon and silica surfaces

Nowak, Stanislaw H. ; Banaś, D. ; Błachucki, Wojciech Maria ; Cao, Wei ; Dousse, Jean-Claude ; Hönicke, P. ; Hoszowska, Joanna ; Jabłoński, Ł. ; Kayser, Yves ; Kubala-Kukuś, A. ; Pajek, M. ; Reinhardt, F. ; Savu, A.V. ; Szlachetko, Jakub

In: Spectrochimica Acta Part B: Atomic Spectroscopy, 2014, vol. 98, p. 65-75

Various 3-dimensional nano-scaled periodic structures with different configurations and periods deposited on the surface of silicon and silica substrates were investigated by means of the grazing incidence and grazing emission X-ray fluorescence techniques. Apart from the characteristics which are typical for particle- and layer-like samples, the measured angular intensity profiles show...

Université de Fribourg

Dissociation of chloromethanes upon resonant σ* excitation studied by x-ray scattering

Bohinc, R. ; Žitnik, M. ; Bučar, K. ; Kavčič, Matjaz ; Journel, L. ; Guillemin, R. ; Marchenko, T. ; Simon, M. ; Cao, Wei

In: The Journal of Chemical Physics, 2014, vol. 139, no. 13, p. 134302

The dissociation process following the Cl K-shell excitation to σ* resonances is studied by high resolution spectroscopy of resonant elastic and inelastic x-ray scattering on CH3Cl, CH2Cl2, CHCl3, and CCl4 molecules. Calculations employing the transition potential and Delta-Kohn-Sham DFT approach are in good agreement with the measured total fluorescence yield and show the presence of...

Université de Fribourg

Testing spatial noncommutativity via magnetic hyperfine structure induced by fractional angular momentum of Rydberg system

Zhang, Jian-Zu ; Liu, Hong-Ping ; Cao, Wei ; Gao, Ke-Lin

In: EPL - Europhysics Letters, 2012, vol. 98, no. 4, p. 40002

An approach to solve the critical problem of testing quantum effects of spatial noncommutativity is proposed. Magnetic hyperfine structures in a Rydberg system induced by fractional angular momentum originated from spatial noncommutativity are discussed. The orders of the corresponding magnetic hyperfine splitting of the spectrum ~10−7–10− 8 eV lie within the limits of accuracy of current...

Université de Fribourg

Depth profiling of dopants implanted in Si using the synchrotron radiation based high-resolution grazing emission technique

Kayser, Yves ; Banaś, D. ; Cao, Wei ; Dousse, Jean-Claude ; Hoszowska, Joanna ; Jagodziński, P. ; Kavčič, Matjaz ; Kubala-Kukuś, A. ; Nowak, S. ; Pajek, M. ; Szlachetko, Jakub

In: X-Ray Spectrometry, 2012, vol. 41, no. 2, p. 98-104

We report on the surface-sensitive grazing emission X-ray fluorescence technique combined with synchrotron radiation excitation and high-resolution detection to realize depth-profile measurements of Al-implanted Si wafers. The principles of grazing emission measurements as well as the benefits offered by synchrotron sources and wavelength-dispersive detection setups are presented. It is shown...

Université de Fribourg

First observation of two-electron one-photon transitions in single-photon K-Shell double ionization

Hoszowska, Joanna ; Dousse, Jean-Claude ; Szlachetko, Jakub ; Kayser, Yves ; Cao, Wei ; Jagodziński, P. ; Kavčič, Matjaz ; Nowak, S. H.

In: Physical Review Letters, 2011, vol. 107, no. 5, p. 053001

xperimental evidence for the correlated two-electron one-photon transitions (1s⁻²→2s⁻¹2p⁻¹) following single-photon K-shell double ionization is reported. The double K-shell vacancy states in solid Mg, Al, and Si were produced by means of monochromatized synchrotron radiation, and the two-electron one-photon radiative transitions were observed by using a wavelength dispersive...

Université de Fribourg

Resonant inelastic x-ray scattering at the limit of subfemtosecond natural lifetime

Marchenko, T. ; Journel, L. ; Marin, T. ; Guillemin, R. ; Carniato, S. ; Žitnik, M. ; Kavčič, Matjaz ; Bučar, K. ; Mihelič, A. ; Hoszowska, Joanna ; Cao, Wei ; Simon, M.

In: The Journal of Chemical Physics, 2011, vol. 134, no. 14, p. 144308

We present measurements of the resonant inelastic x-ray scattering (RIXS) spectra of the CH3I molecule in the hard-x-ray region near the iodine L2 and L3 absorption edges. We show that dispersive RIXS spectral features that were recognized as a fingerprint of dissociative molecular states can be interpreted in terms of ultrashort natural lifetime of ∼200 attoseconds in the case of the iodine...