Perfeziona i miei risultati

Document type

Collection spécifique

Lingua

Université de Fribourg

Not just fundamental research: education, equal opportunities, knowledge and technology transfer, and communication at the nccr bio-inspired materials

Capper, Scott ; Haskal, Eliav ; Kilbinger, Andreas ; Montero de Espinosa, Lucas ; Rothen-Rutishauser, Barbara ; Rüegg, Curzio ; Weder, Christoph

In: CHIMIA International Journal for Chemistry, 2019, vol. 73, no. 1, p. 86–89

Besides conducting excellent fundamental research in domains of strategic importance, the National Centers of Competence in Research (NCCRs) also aim to become centers of reference for education, equal opportunities, and knowledge and technology transfer. These activities are supported by a communication strategy focused on specific target groups. This article describes some of the main...

Université de Fribourg

Functional polymers through mechanochemistry

Schrettl, Stephen ; Balkenendea, Diederik W. R. ; Calvino, Céline ; Karman, Marc ; Lavrenova, Anna ; Neumann, Laura N. ; Sagaraa, Yoshimitsu ; Verde-Sestoa, Ester ; Giannantonio, Michela di ; Simon, Yoan C. ; Fromm, Katharina M. ; Lattuada, Marco ; Weder, Christoph

In: CHIMIA International Journal for Chemistry, 2019, vol. 73, no. 1, p. 7–11

While coupling mechanical and chemical processes is widespread in living organisms, the idea to harness the mechanically induced dissociation of weak covalent and non- covalent bonds to create artificial materials that respond to mechanical stimulation has only recently gained attention. Here we summarize our activities that mainly revolve around the exploitation of non-covalent interactions...

Université de Fribourg

Emergence of nanoplastic in the environment and possible impact on human health

Lehner, Roman ; Weder, Christoph ; Petri-Fink, Alke ; Rothen-Rutishauser, Barbara

In: Environmental Science & Technology, 2019, vol. 53, no. 4, p. 1748–1765

On account of environmental concerns, the fate and adverse effects of plastics have attracted considerable interest in the past few years. Recent studies have indicated the potential for fragmentation of plastic materials into nanoparticles, i.e., “nanoplastics,” and their possible accumulation in the environment. Nanoparticles can show markedly different chemical and physical properties...

Université de Fribourg

Triggered metal ion release and oxidation: ferrocene as a mechanophore in polymers

Giannantonio, Michela Di ; Ayer, Mathieu A. ; Verde-Sesto, Ester ; Lattuada, Marco ; Weder, Christoph ; Fromm, Katharina M.

In: Angewandte Chemie International Edition, 2018, vol. 57, no. 35, p. 11445–11450

The introduction of mechanophores into polymers makes it possible to transduce mechanical forces into chemical reactions that can be used to impart functions such as self‐healing, catalytic activity, and mechanochromic response. Here, an example of mechanically induced metal ion release from a polymer is reported. Ferrocene (Fc) was incorporated as an iron ion releasing mechanophore into...

Université de Fribourg

Speckle-visibility spectroscopy of depolarized dynamic light scattering

Bossert, David ; Natterodt, Jens ; Urban, Dominic A. ; Weder, Christoph ; Petri-Fink, Alke

In: The Journal of Physical Chemistry B, 2017, vol. 121, no. 33, p. 7999–8007

We show that the statistical analysis of photon counts in depolarized dynamic light scattering experiments allows for the accurate characterization of the rotational Brownian dynamics of particles. Unlike photon correlation spectroscopy, the technique is accurate even at low temporal resolution and enables discontinuous data acquisition, which offers several advantages. To demonstrate the...

Université de Fribourg

Approaches to Polymeric Mechanochromic Materials

Calvino, Céline ; Neumann, Laura ; Weder, Christoph ; Schrettl, Stephen

In: Journal of Polymer Science, Part A: Polymer Chemistry, 2017, p. 640-652