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Transport properties of solid state crown ether channel systems

Fromm, Katharina M. ; Bergougnant, Rémi D.

In: Solid State Sciences, 2007, vol. 9, no. 7, p. 580-587

Single crystals of [(H₂O)⊂(DB18C6)(μ₂-H₂O)2/2][(H₃O)⊂(DB18C6)(μ₂-H₂O)2/2]I₃ 1 were shown to possess ideally stacked crown ether molecules which form channels running in one direction through the solid state structure. By immersion of single crystals of 1 into NaOH, ion exchange takes place to yield the compound...