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    Université de Fribourg

    CFA-2 and CFA-3 (Coordination Framework Augsburg University-2 and -3); novel MOFs assembled from trinuclear Cu(I)/Ag(I) secondary building units and 3,3′,5,5′-tetraphenyl-bipyrazolate ligands

    Grzywa, Maciej ; Geßner, Christof ; Denysenko, Dmytro ; Bredenkötter, Björn ; Gschwind, Fabienne ; Fromm, Katharina M. ; Nitek, Wojciech ; Klemm, Elias ; Volkmer, Dirk

    In: Dalton Transactions, 2013, vol. 42, no. 19, p. 6909–6921

    The syntheses of H₂-phbpz, [Cu₂(phbpz)]·2DEF·MeOH (CFA-2) and [Ag₂(phbpz)] (CFA-3) (H₂-phbpz = 3,3′,5,5′-tetraphenyl-1H,1′H-4,4′-bipyrazole) compounds and their crystal structures are described. The Cu(I) containing metal–organic framework CFA-2 crystallizes in the tetragonal crystal system, within space...