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Université de Fribourg

Towards cardiolite-inspired carbon monoxide releasing molecules – Reactivity of d4, d5 rhenium and d6 manganese carb­onyl complexes with isocyanide ligands

Kottelat, Emmanuel ; Chabert, Valentin ; Crochet, Aurélien ; Fromm, Katharina M. ; Zobi, Fabio

In: European Journal of Inorganic Chemistry, 2015, vol. 2015, no. 34, p. 5628–5638

Carbon monoxide releasing molecules (CORMs) are investigated widely in synthetic and medicinal chemistry owing to the potential therapeutic applications of the CO gas. Organometallic carbonyl complexes are best suited to play the role of CO carriers as they allow the exogenous release of CO under controlled conditions, and the toxicity of the gas can be overcome. With the long-term goal of...