New safety-catch photolabile protecting group
- Riguet, Emmanuel Department of Chemistry, University of Fribourg, Switzerland
- Bochet, Christian G. Department of Chemistry, University of Fribourg, Switzerland
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30.11.2007
Published in:
- Organic Letters. - 2007, vol. 9, no. 26, p. 5453 -5456
English
Photolabile protecting groups have proven their usefulness on many occasions. Their versions as linkers are however less attractive, as robustness and real orthogonality become critical issues. Safety-catch systems, where a preliminary activation phase is necessary, circumvent the problem of premature cleavage. In this work, we introduce a new safety-catch photolabile protecting group, whose cleavage requires the simultaneous presence of light and a chemical promoter.
- Faculty
- Faculté des sciences et de médecine
- Department
- Département de Chimie
- Language
-
- English
- Classification
- Chemistry
- License
- License undefined
- Identifiers
-
- RERO DOC 9727
- DOI 10.1021/ol702327c
- Persistent URL
- https://folia.unifr.ch/unifr/documents/300858
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