Faculté des sciences

Synthesis of (E)- and (Z)-1-Thiocyanatobuta-1,3-dienes and their Diels-Alder Reaction

Huber, Stefan ; Stamouli, Peristera ; Neier, Reinhard

In: Journal of the Chemical Society, Chemical Communications, 1985, vol. 9, p. 533-534

1-Thiocyanatobuta-1,3-dienes react with strong dienophiles to produce directly the rearranged products of type (6) via a combination of a Diels-Alder reaction with a [3,3] sigmatropic shift. Plus

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    Summary
    1-Thiocyanatobuta-1,3-dienes react with strong dienophiles to produce directly the rearranged products of type (6) via a combination of a Diels-Alder reaction with a [3,3] sigmatropic shift.