Faculté des sciences

Mild and rational synthesis of palladium complexes comprising C(4)-bound N-heterocyclic carbenes

Kluser, Evelyne ; Neels, Antonia ; Albrecht, Martin

In: Chemical Communications, 2006, p. 4495-4497

Oxidative addition of pyridyl-functionalised 4-iodoimidazolium salts to palladium(0) gives catalytically active complexes in which the N-heterocyclic carbene is bound to the palladium(II) centre in a non-classical bonding mode via C(4). More

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    Summary
    Oxidative addition of pyridyl-functionalised 4-iodoimidazolium salts to palladium(0) gives catalytically active complexes in which the N-heterocyclic carbene is bound to the palladium(II) centre in a non-classical bonding mode via C(4).