Faculté des sciences
Texte intégral

A liquid-crystalline hexa-adduct of [60]fullerene

Chuard, Thierry ; Deschenaux, Robert ; Hirsch, Andreas ; Schönberger, Hubert

In: Chemical Communications, 1999, p. 2103 - 2104

A hexa-adduct of [60]fullerene was synthesized by addition of a mesomorphic twin cyanobiphenyl malonate derivative to C60; whereas the malonate derivative gave a monotropic nematic phase, the fullerene hexa-adduct showed an enantiotropic smectic A phase. More

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    Title
    • A liquid-crystalline hexa-adduct of [60]fullerene
    Author
    • Chuard, Thierry. Institut de Chimie, Université de Neuchâtel, Switzerland
    • Deschenaux, Robert. Institut de Chimie, Université de Neuchâtel, Switzerland
    • Hirsch, Andreas. Institut für Organische Chemie, Universität Erlangen-Nürnberg, Erlangen, Germany
    • Schönberger, Hubert. Institut für Organische Chemie, Universität Erlangen-Nürnberg, Erlangen, Germany
    Document Type
    • Postprint
    Publication Date
    • 1999
    Language
    • English
    Published in
    • Chemical Communications, 1999, p. 2103 - 2104. Royal Society of Chemistry
    Other Version
    Classification
    • Chemistry
    OAI-PMH Identifier
    • oai:doc.rero.ch:20061113103207-FW
    Submission No.
    • 20061113103207-FW
    Summary
    A hexa-adduct of [60]fullerene was synthesized by addition of a mesomorphic twin cyanobiphenyl malonate derivative to C60; whereas the malonate derivative gave a monotropic nematic phase, the fullerene hexa-adduct showed an enantiotropic smectic A phase.