Faculté des sciences
Texte intégral

Oxygenation of alkanes with hydrogen peroxide catalysed by osmium complexes

Shulpin, Georgiy B. ; Süss-Fink, Georg ; Shulpina, Lidia S.

In: Chemical Communications, 2000, p. 1131-1132

Efficient oxidation of alkanes, including methane and ethane, with H2O2 in the presence of catalytic amount of an Os complex in MeCN (addition of nitrogen-containing heterocycles significantly enhances the yield of the products) or in MeCO2H gives the corresponding ketones and alcohols. More

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    Title
    • Oxygenation of alkanes with hydrogen peroxide catalysed by osmium complexes
    Author
    • Shulpin, Georgiy B.. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, Russia
    • Süss-Fink, Georg. Institut de Chimie, Université de Neuchâtel, Switzerland
    • Shulpina, Lidia S.. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia
    Document Type
    • Postprint
    Publication Date
    • 2000
    Classification
    • Chemistry
    OAI-PMH Identifier
    • oai:doc.rero.ch:20060508162820-OZ
    Submission No.
    • 20060508162820-OZ
    Summary
    Efficient oxidation of alkanes, including methane and ethane, with H2O2 in the presence of catalytic amount of an Os complex in MeCN (addition of nitrogen-containing heterocycles significantly enhances the yield of the products) or in MeCO2H gives the corresponding ketones and alcohols.