Faculté des sciences

Elimination of sulfur from aromatic heterocycles by a water-soluble arene ruthenium cluster: synthesis and molecular structure of [H2S2Ru4(C6H6)4]Cl2

Chérioux, Frédéric ; Therrien, Bruno ; Süss-Fink, Georg

In: Chemical Communications, 2004, p. 204-205

C–S bond cleavage in thiophene, benzothiophene and dibenzothiophene is achieved under biphasic conditions by the water-soluble cluster cation [H4Ru4(C6H6)4]2+ which is converted into the disulfido cluster [H2S2Ru4(C6H6)4]2+. Plus

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    Summary
    C–S bond cleavage in thiophene, benzothiophene and dibenzothiophene is achieved under biphasic conditions by the water-soluble cluster cation [H4Ru4(C6H6)4]2+ which is converted into the disulfido cluster [H2S2Ru4(C6H6)4]2+.