Faculté des sciences

Novel HEXOL-type cyclometallated iridium(III) complexes: stereoselective synthesis and structure elucidation

Yang, Liangru ; Zelewsky, Alexander von ; Stoeckli-Evans, Helen

In: Chemical Communications, 2005, vol. (33), p. 4155

Two diastereoisomers of tetranuclear cyclometallated iridium complexes, either having an inner core of HEXOL-type [Ir(IrCl₂)₃]⁶⁺ unit and a surface of six chiral, didentate, cyclometallated ligands, are stereoselectively synthesized from an enantiopure pinenopyridine derivative. More

Add to personal list
    Summary
    Two diastereoisomers of tetranuclear cyclometallated iridium complexes, either having an inner core of HEXOL-type [Ir(IrCl₂)₃]⁶⁺ unit and a surface of six chiral, didentate, cyclometallated ligands, are stereoselectively synthesized from an enantiopure pinenopyridine derivative.