Settling and compaction of chromite cumulates employing a centrifuging piston cylinder and application to layered mafic intrusions
Manoochehri, Shahrzad ; Schmidt, Max
In: Contributions to Mineralogy and Petrology, 2014, vol. 168, no. 6, p. 1-20
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- The time scales and mechanics of gravitationally driven crystal settling and compaction is investigated through high temperature (1,280-1,500°C) centrifuge-assisted experiments on a chromite-basalt melt system at 100-1,500g (0.5 GPa). Subsequently, the feasibility of this process for the formation of dense chromite cumulate layers in large layered mafic intrusions (LMIs) is assessed. Centrifugation leads to a single cumulate layer formed at the gravitational bottom of the capsule. The experimentally observed mechanical settling velocity of a suspension of ~24vol% chromite is calculated to be about half (~0.53) of the Stokes settling velocity, with a sedimentation exponent n of 2.35 (3). Gravitational settling leads to an orthocumulate layer with a porosity of 0.52 (all porosities as fraction). Formation times for such a layer from a magma with initial chromite contents of 0.1-1vol% are 140-3.5days, equal to a growth rate of 0.007-0.3m/day for grain sizes of 1-2mm. More compacted chromite layers form with increasing centrifugation time and acceleration through chemical compaction: An increase of grain contact areas and grain sizes together with a decrease in porosity is best explained by pressure dissolution at grain contacts, reprecipitation and grain growth into the intergranular space and a concomitant expulsion of intergranular melt. The relation between the porosity in the cumulate pile and effective pressure integrated over time (Δρ·h·a·t) is best fit with a logarithmic function, in fact confirming that a (pressure) dissolution-reprecipitation process is the dominant mechanism of compaction. The experimentally derived equation allows calculating compaction times: 70-80% chromite at the bottom of a 1-m-thick chromite layer are reached after 9-250years, whereas equivalent compaction times are 0.2-0.9years for olivine (both for 2mm grain size). The experiments allow to determine the bulk viscosities of chromite and olivine cumulates to be of magnitude 109Pas, much lower than previously reported. As long as melt escape from the compacting cumulate remains homogeneous, fluidization does not play any role; however, channelized melt flow may lead to suspension and upward movement of cumulate crystals. In LMIs, chromitite layers are typically part of a sequence with layers of mafic minerals, compaction occurs under the additional weight of the overlying layers and can be achieved in a few years to decades.