Faculté des sciences

[Bis(2-pyridyl-κN)amine]chlorido(η6-hexamethylbenzene)ruthenium(II) hexafluoridophosphate dichloromethane solvate

Gupta, Gajendra ; Therrien, Bruno ; Kim, Jinkwom

In: Acta Crystallographica Section E : Structure Reports Online, 2011, vol. E67, no. 5, p. m548

In the title half-sandwich complex, [RuCl(η6-C12H18)(C10H9N3)]PF6•CH2Cl2, the ruthenium(II) ion is four-coordinated by a chloro, a hexamethylbenzene and a bidentate N, N'-chelating di(pyridin-2-yl)amine ligand. In the crystal, the amino N-H group forms a hydrogen bond with the... Plus

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    Summary
    In the title half-sandwich complex, [RuCl(η6-C12H18)(C10H9N3)]PF6•CH2Cl2, the ruthenium(II) ion is four-coordinated by a chloro, a hexamethylbenzene and a bidentate N, N'-chelating di(pyridin-2-yl)amine ligand. In the crystal, the amino N-H group forms a hydrogen bond with the chloro ligand of a neighbouring complex, thus forming chains along the b axis. Weak intermolecular C-H...F and C-H... Cl contacts are also observed.