Faculté des sciences

Dichlorido(furfurylamine-κN)(η6-hexamethylbenzene)ruthenium(II)

Garci, Amine ; Thai, Trieu-Tien ; Süss-Fink, Georg ; Therrien, Bruno

In: Acta Crystallographica Section E, 2011, vol. E67, no. 11, p. m1592

The single-crystal X-ray structure analysis of [RuCl2(C12H18)(C5H7NO)] reveals a distorted piano-stool geometry around the RuII atom, with a hexamethylbenzene ligand, two chloride ligands and a furfurylamine ligand, the latter coordinating through the amine group. In the crystal, a dimeric structure is observed as a result of... Plus

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    Summary
    The single-crystal X-ray structure analysis of [RuCl2(C12H18)(C5H7NO)] reveals a distorted piano-stool geometry around the RuII atom, with a hexamethylbenzene ligand, two chloride ligands and a furfurylamine ligand, the latter coordinating through the amine group. In the crystal, a dimeric structure is observed as a result of N-H...Cl interactions between two symmetry-related molecules.