Faculté des sciences

Rhodium(I) iminophosphine poly(propyleneimine) dendrimers: Synthesis, characterization and molecular structure of a mononuclear analogue

Antonels, Nathan C. ; Therrien, Bruno ; Moss, John R. ; Smith, Gregory S.

In: Inorganic Chemistry Communications, 2009, vol. 12, no. 8, p. 716-719

First (G1)- and second-generation (G2) poly(propyleneimine) (PPI) dendrimers were reacted with 2-(diphenylphosphino)benzaldehyde, to form iminophosphine-functionalised dendritic ligands (1, 2). The reaction of the dimeric precursor [RhCl(CO)2]2 with the heterobidentate dendritic ligands 1, 2 gave the corresponding rhodium(I)... Plus

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    Summary
    First (G1)- and second-generation (G2) poly(propyleneimine) (PPI) dendrimers were reacted with 2-(diphenylphosphino)benzaldehyde, to form iminophosphine-functionalised dendritic ligands (1, 2). The reaction of the dimeric precursor [RhCl(CO)2]2 with the heterobidentate dendritic ligands 1, 2 gave the corresponding rhodium(I) complexes (3, 4).