Faculté des sciences

Stereoselective synthesis of cyclometalated iridium(III) complexes: characterization and photophysical properties

Yang, Liangru ; Zelewsky, Alexander von ; Nguyen, Huong P. ; Muller, Gilles ; Labat, Gaël Charles ; Stoeckli-Evans, Helen

In: Inorganica Chimica Acta, 2009, vol. 36, no. 10, p. 3853-3856

The stereoselective synthesis of a highly luminescent neutral Ir(III) complex comprising two bidentate chiral, cyclometalating phenylpyridine derivatives, and one acetylacetonate as ligands is described. The final complex and some intermediates were characterized by X-ray structural analysis, NMR-, CD-, and CPL-spectroscopy. Plus

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    Summary
    The stereoselective synthesis of a highly luminescent neutral Ir(III) complex comprising two bidentate chiral, cyclometalating phenylpyridine derivatives, and one acetylacetonate as ligands is described. The final complex and some intermediates were characterized by X-ray structural analysis, NMR-, CD-, and CPL-spectroscopy.